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TinyMCE is a crossbrowser RTE: if a function like this only works in IE it should not be in there at all.
You can download the IESpell ActiveX control from here.
http://www.iespell.com/download.php
tinyMCE.init({
theme : "advanced",
mode : "textareas",
plugins : "iespell",
theme_advanced_buttons3_add : "iespell"
});
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The WYSIWYG editing component for developers anywhere, everywhere, anytime and with any content.